×
The submission system is temporarily under maintenance. Please send your manuscripts to
Go to Editorial ManagerThe presence of heavy metal pollutants in refinery effluent significantly impacts the corrosion rate of carbon steel. The focus of this research is to analyze the impact of various inorganic pollutants, including copper, vanadium, nickel, and chromium ions, on the corrosion of carbon steel across different solutions. After conducting a thorough examination of various operating conditions, including pollutant concentration (ranging from 300-3000 ppm), temperature (30-60? C), and flow velocity (0-800 rpm). Our research shows that copper ions have the highest corrosion rate, with vanadium ions being a close second. Conversely, nickel and chromium had the most negligible impact on corrosion rate and, in some instances, even exhibited corrosion inhibition effects. It was also observed that an increase in flow velocity and temperature significantly amplified the corrosion rate of the metal ions investigated.
The heavy metals are considered dangerous pollutants which harm health and environment. The adsorption process is the cost effective process to get-rid of heavy metal efficiently. In this study, the adsorption bed of Nickel is simulated by using COMSOL Multiphysics to find the effect of different operating parameters namely; flow rate, temperature and pollutant concentration on adsorption bed efficiency. The modeling of non-isothermal adsorption bed based on experimental isotherms kinetic of previous work is developed too. The results showed that the optimal conditions to generate maximum removal efficiency of heavy metal were at 50?C inlet temperature, 0.1 M inlet concentration, and 80 ml/min flow rate to achieve removal values higher than 50 % of long operation period time.
The hydrodynamics of stirred tanks and bubble breakup are crucial in gas-liquid flows, yet this system has not been well characterized for different operating conditions. In this work, the numerical method was used to investigate the hydrodynamics of six- flat blades impeller (Rushton turbine) and the results were employed to understand the bubble breakup behavior in the stirred tank. Simulation results of predicted flow pattern, power number, and the distribution of turbulence energy generated were performed with COMSOL Multiphysics. Numerical results showed good agreement with the experimental literature. The effect of rotational speed on bubble breakup behavior, such as breakage probability, the average number of daughter bubbles, and the breakage time was investigated using the high-speed imaging method. The main finding is that the breakage process occurs in the high energy area of high turbulence intensity, which is located within a distance equal to the blade width of a radius of (15-35 mm). The breakage probability (Bp) was found to be increased by 12.61 percent for a mother bubble of 4 mm at 340 rpm, with an average fragmentation of up to 22 fragments. Furthermore, the bubble breakage time was found to decrease with increasing impeller rotational speed, with an average value of 19.8 ms.
The electrodes material plays an important role in the amount of electricity produced in microbial fuel cells (MFCs). Metal electrodes used in MFCs are subject to biological and concentration cell corrosion which leads to a decrease in the cell efficiency. In the present work, the corrosion behavior of three selected electrode materials, namely, stainless steel, copper, and zinc under different operating conditions was investigated and discussed. In anode chamber, the microorganism (MO) used was Saccharomyces cerevisiae (yeast) with sodium acetate as a substrate forming the microbial corrosive solution. In the cathode chamber, the corrosive solution is aerated water. The effects of different operating parameters on the corrosion rate (CR) of these electrodes were studied such as: microorganism concentration, aeration of cathode chamber, and flow velocity in cathode chamber. The potential of the each electrode was measured to understand the corrosion behavior of electrodes and the produced current was also investigated. It was found that the corrosion rate of the electrodes in both anode and cathode chambers increases with increasing MO concentration in anode chamber and with increasing agitation speed in cathode chamber. The bio-corrosion is an important part of the corrosion occurring in microorganism chamber. The stainless steel exhibited the lowest corrosion rate for the whole investigated range of operating parameters followed by copper. The zinc electrode was found to be poor as an electrode in MFC as its corrosion rate was very high in all conditions investigated. In addition, this study showed that the air pumping in water chamber causes an appreciable increase in the corrosion rate in both chambers and an increase in the produced current.
An experimental study on single bubble breakage in the stirred tank in oil as a continuous phase was carried out for a range of stirring speeds (220 to 430 rpm). The results are compared with bubble breakage in water that was conducted by Hasan et al. (2021) to investigate the effect of physical properties of continuous phase on the breakage rate. The breakage events in the impeller were captured and analyzed using a high speed camera. It was found that the breakage rate represented by breakage probability and a number of produced daughter bubbles (fragments) are directly proportional with the stirring speed. The breakage probability and number of produced daughter bubbles in oil was noticeably lower than that in water indicating the role the continuous phase viscosity plays in reducing the breakage rate.
The impact of flow velocity (0-900 rpm) on the corrosion rate of carbon steel in a wide range of sulfuric acid concentrations (0-90% in H2O) at 30 °C and 1 h was studied and discussed. In addition, the efficiency of corrosion inhibitor (dimethyl disulfide, DMD) was evaluated in hardest corrosion conditions for the range of velocity investigated. The results revealed that increasing the flow velocity of H2SO4 solution, increases the corrosion rate depending on the acid concentration. When the flow velocity is increased of H2SO4 solution, the corrosion potential was shifted to more negative. The DMD inhibitors showed significant inhibition efficiency at high velocities, where the highest percentage of inhibitor efficiency reached 98% at 900 rpm.
The breakage rate of liquid drops in the dispersed phase is a key way to improve the heat and mass transfer between the continuous/dispersed phases. This work includes a review of experimental results of liquid drop breakage in an agitated tank. The study highlighted the experimental conditions that were investigated as well as the important findings about the impact of operating conditions on some breakup parameters. The conflicts and discrepancies in the findings of those studies were identified and analyzed. The review found that many experimental parameters affect the drop breakage rate. The breakage probability (BP), number of fragments, and breakage time (BT) are direct functions of power input.