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Go to Editorial ManagerThe present work deals with direct diffusion bonding welding without interlayer of austenitic stainless steel type AISI 304L with Oxygen Free High Conductivity pure copper (OFHC) in vacuum atmosphere (1.5 *10-5 mbr.). The optimum bonding conditions are temperature of 650 ?C, duration time of 45 min. and the applied stress of 30 MPa, in order to secure a tight contact between the mating surfaces. The corrosion behavior of diffusion bonding joints in 3.5% Nacl is studied to evaluate the corrosion resistance of welding joints by using Potentiodynamic method. The observed microstructure of corroded specimen of optimum diffusion bonding joint shows that the corrosion current density has low value as compared with base materials used. During polarization, galvanic coupling is observed between two materials used. At passivity region, inverse polarity is occurred at 450mV. Therefore, passive stainless steel 304 L behaves as cathode respective to pure copper, the corrosion behavior of the diffusion bonding joint was mostly by copper side. The corrosion results indicate the presence of galvanic effect. The corrosion current density of copper, stainless steel 304L and bond joints condition were (3.66 µA/cm2, 1.62 µA/cm2 and 1.85µA/cm2) respectively. A SEM examination of corroded diffusion bonding joint indicates that the galvanic corrosion happened on copper side. The corrosion rate of bonding joint conditions was 0.85 mpy, which is less than 1%. This means that corrosion resistance of bond joint is more than excellent.
In the present work, the agricultural wastes which are wheat bran and raw okra waste used as adsorbent material for adsorption of cadmium and copper ions from wastewater .The effect of adsorption variable which include initial pH of solution , agitation speed, agitation time, initial concentration of cadmium and copper ions, and amount of adsorbent material were investigated in a batch process in order to obtain the maximum ions removal from wastewater .The results obtained from experimental investigation show that the percentage removal of metal ions increases with increasing pH and agitation speed until a maximize value after that it decreased with increasing pH and agitation speed. Also increases with increasing amount of adsorbent material and agitation time until a maximize value then reach a constant value approximately , and decreasing with increasing metal ions concentration .The maximum removal percent of cadmium and copper ions were 85.8% and 52.7 % respectively which obtained at pH equal 5.0, agitation speed 150 revolution per minute, agitation time 105 minute , metal ion concentration 40mg /L ,and adsorbent amount 1.5gm when using wheat bran as adsorbent material ,while obtained the maximum removal percent of cadmium and copper ions were 81.7% and 47.8 % which obtained at pH equal 6.0, and pH equal 5.0 respectively , agitation speed 150 revolution per minute, agitation time 90 minute ,metal ion concentration 40 mg /L ,and adsorbent amount 1.5gm when using okra waste as adsorbent material. From above result the wheat bran and okra waste was a best adsorbent material for removal cadmium and copper ions from wastewater but wheat bran slightly more effective than okra waste._x000D_
Platinum, copper, and nickel were founded the best metals used in resistance temperature detectors RTDs. They commonly used in laboratory and industrial applications because they provide accurate and reliable measurements in a wide temperature range from (- 200 to 850 °C). They have high conductivity, sensitivity, and hardness to resist strain shock, pressure, and vibration. The accuracy level of them depends on reliability, stability, repeatability, linearity, and response to time. This study aims to determine and compare the accuracy of these three metals in regarding to their features which include stability, repeatability, and response time. The study has gathered and analyzed the data of these suitable and precise metals and compared with each other. The results showed that platinum is widely needed for RTDs due to its precision, stability, higher accuracy, and linearity output, while copper and nickel are not stable or repeatable as platinum. It was indicated that temperature coefficient of resistance TCR for nickel is bigger and for copper is medium, but for platinum is lower.
Recently, major part of convection heat transfer researches focus on increasing fins efficiency by increasing thermal performance for the same fin volume. Metal foam is a promising way to achieve this aim. Performance analysis has been carried out to investigate the heat transfer characteristics of copper fin foam samples. The samples have been compared with the solid metal fin heat transfer. A forced convection heat transfer had been applied to a four specimens. An electrical heater heats up the fins, which are subjected to a stream of the ambient air driven by a blower fan as heat dissipated. The heat flux had been fixed along the tests with three different air velocity used; the forced heat convection had been simulated. The pores density of copper fin foam is varied in the range of 10, 20 & 40 pores per inches (PPI). Thermal performance of copper fin foam has been evaluated in terms of average Nusselt number and thermal resistance of heat sinks. The increasing in the heat transfer rate and average Nusselt number when used metal foam has been found in the range of 36-133 % compare to solid copper. Furthermore, it has been proven that this increment reaches the maximum value for a given PPI even when raise the air velocity.
An experimental study was conducted to investigate the mass transport behavior for electrochemical reduction of copper in the presence of 0.5M H2SO4 as supporting electrolyte by limiting current technique (LCT). The experiments were carried out via rotating cylinder electrode made of copper as cathode. The effects of various operating conditions: rotation rates 100, 200, 300, 400, and 500rpm, electrolyte temperatures 30, 45, and 60?, and cupric ions concentration 250, 500, and 750 ppm on mass transfer rate were studied. It was observed that mass transfer coefficient based mainly on rotation rates, then temperature and finally cupric ions concentration. The electrodeposition of cupric ions was proved to be a mass control. The mass transfer coefficient for rotating cylinder electrode was correlated with the aid of dimensionless groups as follows:Sh = 0.236 Re0.664 Sc0.356And the above correlation is a good agreement with eisenberg equation.
Galvanic corrosion of Nickel-Chrome alloy (Ni-Cr alloy) and Copper (Cu) coupled in 5% sulfuric acid solution was investigated. The effects of agitation velocity, temperature, and time on the galvanic corrosion current and the weight loss of both metals in both free corrosion and galvanic corrosion were investigated. The trends of open circuit potential (OCP) of each metal and galvanic potential (Eg) of the couple were also determined. The results showed that Cu was cathodic relative to Ni-Cr alloy in galvanic couple and the corrosion potential of the couple (Ni- Cr alloy /Cu) was between the values of the two single components because the OCP of copper shifted to positive with the increase in velocity. Under stagnant conditions initially the galvanic current was more negative then shifted to the positive with time. The corrosion of Ni-Cr alloy decreased with time because the passivation layer was formed on the surface. Under flow conditions, the galvanic current sharply shifted to the negative direction (increase galvanic current from Ni-Cr alloy (anode) to Cu (cathode) during the first few minutes.
The experimental analysis is conducted under the Iraqi climate conditions to investigate the performance enhancement of a solar updraft tower system (SUTS) using the porous copper foam as an absorber plate and conventional absorber plate with absorber inclination angle of 18°. In the present work, a semicircular collector is divided into two identical quarter thermal collectors to become two identical SUTS. One of the quarter circular thermal collectors contains on the metal foam as an absorber plate, while the other quarter collector on the conventional flat copper absorber plate. In this study the air inlet height is changed of (3, 5, and 8) cm. The experimental tests carried out in Baghdad city (latitude 33.3° N). Results showed that the air inlet height variation caused to enhance the solar updraft tower performance. The highest values was recorded when the air inlet height is 3 cm using porous absorber compared to flat absorber plate. Copper material foam as an endothermic surface causes a marked decrease in average surface temperature of the plate. The maximum hourly thermal efficiency of solar collector was increased to about 41.6 % and the maximum enhancement of the power output to about 45.2 % compared with flat absorber plate.
The efficiency of adsorption using copper nanocomposite catalysts for the removal of lead ions from aqueous solution was studied. Nano copper and its nanocomposition were prepared in laboratory in very accurate conditions. After preparing samples, the samples were analyzed using XRD and SEM and that shows very good morphology of catalytic performance and has nano sized of crystalline shape. In order to study the efficiency of these catalysts, all samples were tested using adsorption process. The preparing samples show very good efficiency for lead removing from aqueous solution, and reach maximum removal efficiency 96% for 0.05g of adsorbents at pH 10, otherwise increasing or decreasing the pH would give undesirable results for all samples. Langmuir isotherm fitted better than Freundlich isotherm for adsorption of lead.
The adsorptions of copper ions from aqueous solution by can papyrus were studied using batch and continuous adsorption. It has been improved surface area and efficiency of the cane papyrus using urea and thiurea at different concentrations through stirring in period of time with mixer. Results proved that cane papyrus very well in the adsorption of metal through the study of important variables and influences such as the contact time, pH in addition to the initial concentration. It was found that the effect of pH at 6 to 7 better than acid or base solution also found that the best time for adsorption to reach equilibrium is 90min and there is no effect of temperature significantly on the results observed, studied the effect of weight of the cane where found that 0.4g best weight. After treatment with urea and thiurea the results improved from the 56% removal by natural cane, 61% for urea modified and 68% for thiurea modified. For continuous adsorption the results shows that when the flow rate increase in constant bed of adsorbent the breakthrough decrease. As well as the best curve was obtained using a cane modified with thiurea weighing 2.5g in a continuous flow rate where the breakthrough curve is start from 25min to 175min. The results was applied to Langmuir and Freundlich adsorption isotherms, the results fitted will to both at correlation coefficients 0.971 and 0.9066 for Langmiur and Freundlich respectively. Pseudo second order was applied and gives better results for adsorption where R2 is 0.9941 while for pseudo first order R2 is 0.136.
The electrodes material plays an important role in the amount of electricity produced in microbial fuel cells (MFCs). Metal electrodes used in MFCs are subject to biological and concentration cell corrosion which leads to a decrease in the cell efficiency. In the present work, the corrosion behavior of three selected electrode materials, namely, stainless steel, copper, and zinc under different operating conditions was investigated and discussed. In anode chamber, the microorganism (MO) used was Saccharomyces cerevisiae (yeast) with sodium acetate as a substrate forming the microbial corrosive solution. In the cathode chamber, the corrosive solution is aerated water. The effects of different operating parameters on the corrosion rate (CR) of these electrodes were studied such as: microorganism concentration, aeration of cathode chamber, and flow velocity in cathode chamber. The potential of the each electrode was measured to understand the corrosion behavior of electrodes and the produced current was also investigated. It was found that the corrosion rate of the electrodes in both anode and cathode chambers increases with increasing MO concentration in anode chamber and with increasing agitation speed in cathode chamber. The bio-corrosion is an important part of the corrosion occurring in microorganism chamber. The stainless steel exhibited the lowest corrosion rate for the whole investigated range of operating parameters followed by copper. The zinc electrode was found to be poor as an electrode in MFC as its corrosion rate was very high in all conditions investigated. In addition, this study showed that the air pumping in water chamber causes an appreciable increase in the corrosion rate in both chambers and an increase in the produced current.
The presence of heavy metal pollutants in refinery effluent significantly impacts the corrosion rate of carbon steel. The focus of this research is to analyze the impact of various inorganic pollutants, including copper, vanadium, nickel, and chromium ions, on the corrosion of carbon steel across different solutions. After conducting a thorough examination of various operating conditions, including pollutant concentration (ranging from 300-3000 ppm), temperature (30-60? C), and flow velocity (0-800 rpm). Our research shows that copper ions have the highest corrosion rate, with vanadium ions being a close second. Conversely, nickel and chromium had the most negligible impact on corrosion rate and, in some instances, even exhibited corrosion inhibition effects. It was also observed that an increase in flow velocity and temperature significantly amplified the corrosion rate of the metal ions investigated.
An experimental and theoretical study of free convection heat transfer for a cylinder placed in an iron test section of dimensions (0.2x0.2x0.2 m3), the test section filled with saturated porous material glass balls (5 mm), and the air is the working fluid with Raleigh number (7692.6 ? Ra ? 17654). The circular cylinder heater (D = 0.015 m, L = 0.2 m) is heated electrically, made of Copper and located in different positions (in X & Y direction). The theoretical part includes solving the free convection heat transfer using the ANSYS program (fluent). The experimental and theoretical results showed that the surface temperature values around the cylinder perimeter when changing its position within the test section are changing as moving up and down where the effect of buoyancy force appears. The maximum difference between the upper and lower position at the experimental result is 7.22%, and the average Nusselt number increases with Raleigh number and heat flux. Also, the experimental results showed that the use of porous material significantly improves the heat transfer by 48.6%. The maximum percentage change between the experimental and theoretical results is 5.46%. Moreover, experimental correlations were achieved, and a comparison was performed between the present results with the previous studies and it gives a good agreement.
The present work demonstrates the optimization process of Micro- hole of Electrical Discharge Machining (EDM) by Adaptive Neuro Fuzzy Inference System (ANFIS). The workpiece material was copper alloy. The current, gap distance and pulse on time were the control parameters of EDM. The process has been successfully modeled using ANFIS model constructs a fuzzy inference system in MATLAB 7.2 Software Gaussian type for optimization of micro diameter, were adopted during the training and testing process of ANFIS model in order to compare the prediction accuracy of micro diameter by one membership function. Finally, the comparison of ANFIS results with experimental data indicates that adoption of Gaussian membership function in proposed system achieved satisfactory accuracy. Prediction using ANFIS model compared with experimental values of micro holes at correspond ratio 98.37%.
Hydrogen fuel is a good alternative to fossil fuels. It can be produced using a clean energy without contaminated emissions. This work is concerned with experimental study on hydrogen production via solar energy. Hybrid photovoltaic thermal system (PV/T) is used to convert solar radiation to electrical and thermal energy. The electrical energy is used to analyze water into hydrogen and oxygen by using alkaline water electrolyzer with stainless steel electrodes. The absorbed thermal energy is used to heat circulating water inside the copper serpentine pipe fixed on the back surface of the PV panel. A perforated pipe connected on the upper edge of PV panel is used to spray a thin layer of water on the PV panel surface for auxiliary cooling and improve the generated electrical power. The hydrogen production system is tested at different temperature of electrolysis water (40, 45, 50, 55, 60)?C. The experimental results show that the PV module electrical efficiency is improved by (14.31)%. while the power generated was enhanced by (3.94 to 15.40)%. The maximum hydrogen production rate is 153.3 ml/min, the efficiency of the system is 20.88% and the total amount of hydrogen produced in one day is 220.752 liter.