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Search Results for nano-hydroxyapatite

Article
Fabrication and Optimization of Electrophoretic Deposition Parameters Using Alternating Current by Taguchi Design

Muna Khethier Abbass, Mohammed Jasim Khadhim, Ayad Naseef Jasim, Muhammad Jawad Issa, Khawla Salah Khashan

Pages: 8-15

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Abstract

The aim of this work is to optimize EPD variables (voltage, time, and focus) using alternating current through the Taguchi Design of Experiment (DOE). Coating Nano hydroxyapatite (Nano-HA) on a Ti6Al4V substrate depends on thickness and roughness, then characterization of a coating layer to determine the optimum state. Hydroxyapatite (HAp) powder was deposited on a Ti-6Al-4V alloy substrate by electro-deposition with ethanol as a solvent under AC current, to improve the alloy surface quality based on coating thickness and maximum coating mass meeting the requirements of a biological orthopedics application. Ethanol was used as a solvent to precipitate ketazone and HAp on the base alloy. Taguchi's approach was used in order to determine the optimal conditions for EPD and subsequently to apply various criteria for depositing the biochemical coating. The surface and cross-section composition of the paint is described by characterization. Numerous tests and inspections; Zeta, XRD and SEM stability test, water contact angle and optical microscopes were used to describe the surface morphology of the HAp layer. The value of the optimum conditions for deposition of the HAp layer which is a simultaneous thickness and maximum coating mass, was predicted at a sedimentation voltage of 40 V, 2 min sedimentation time and 1 g / L for the concentration of the suspended solution at room temperature. The validity of the model resulting from the response surface methodology was assessed by comparing the expected results with the experimental results. In addition, close agreement was observed between the experimental results and the expected results. For the solution at room temperature, the results obtained with the highest value of the coating thickness of 41at the surface roughness of 0.94 and the contact angle of the alloy before coating is 67.489º reduced to. 38.132º after plating, which indicates an increase in the harmony of the metal implant and biocompatibility.

Article
Surface modification of 316L Stainless Steel alloy using Nano Ceramic Hydroxyapatite, Magnesium Oxide, Zinc Oxide, and composite coating by EPD to enhancing corrosion resistance in biomedical application

Aya Muhsin Hazber, Ayad Naseef Jasim, Abbas Al-Bawee

Pages: 47-56

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Abstract

The toxicity of permanent implants is the main concern. The release of ions from the substrate leads to toxicity. Because of how the human body works biologically, the toxicity of corrosion compounds is a byproduct of wear and fretting debris. aimed to improve the corrosion resistance of a 316L stainless steel substrate. Bio ceramic Nano-hydroxyapatite (HA) was coated using the Electrophoretic Deposition (EPD) technique. Stainless steel has good mechanical properties and high compatibility, but it suffers from body fluid attack due to its chloride content, which can penetrate the passivation layer, resulting in the release of chromium and nickel ions. Tissues and organs are damaged by the ions and debris that are released. To address this problem, it was coated with bioceramic using the EPD method. Suspensions of various powders—hydroxyapatite, magnesium oxide, zinc oxide, and the composite—were prepared and coated by electrophoretic deposition. The coated samples were dried at room temperature to ensure a homogeneous coating structure. The zeta potential test for magnesium oxide and hydroxyapatite suspensions was positive, while zinc oxide and complex suspensions were negative. One of the important parameters for achieving electrolyte and implant balance is the open circuit potential (OCP). A substantial change towards a more noble direction (less negative) was seen in the OCP-coated (316 L) alloy, suggesting excellent thermodynamic stability. Tafel extrapolation analysis was used to obtain the corrosion potential (Ecorr) and corrosion current density (Icorr) values of composite-coated stainless steel 316L, which are generally derived from the polarization curve. The findings that are in line with the MgO, HA, and ZnO coatings show a significant decrease in corrosion current (Icorr), an increase in corrosion potential (Ecorr), and a decrease in corrosion rate from (4.386 × 10-¹ mm/y) Stainless Steel 316 L to (1.417 × 10-² mm/y) MgO Coated and (1.222 × 10-³ mm/y) (65%MgO+25%ZnO+10%HA coated).

Article
Optimization of Nano Hydroxyapatite/chitosan Electrophoretic Deposition on 316L Stainless Steel Using Taguchi Design of Experiments

Mohammed Jasim Kadhim, Nawal Ezzat Abdullatef, Makarim Hazim Abdulkareem

Pages: 1215-1227

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Abstract

The aim of this work is to determine the optimum parameters for deposition of chitosan and mixture of chitosan and hydroxyapatite (HA) layers using electrophoretic deposition.  The layers were on 316L stainless steel substrate. Taguchi approach was utilized to select the optimum parameters for both layers. The parameters used for deposition chitosan are voltage, time and temperature while the parameters used for HA and chitosan are voltage, time, concentration and temperature. Zeta potential tests were employed to measure the solutions stability.  Coating layers were characterized for thickness, porosity and nanoroughness using optical microscopy (OM) and atomic force microscopy (AFM).  The results from Taguchi design of experiments demonstrated that the best conditions for deposition of chitosan and HA layers are  50 V, 5 min, 3 g HA/L and 30°C.    The corresponding thickness, % porosity, nanoroughness and microroughness for optimum conditions were 22 µm, 3.53,  4.48 nm and 3.85 µm respectively.

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