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Go to Editorial ManagerIn the present work, the agricultural wastes which are wheat bran and raw okra waste used as adsorbent material for adsorption of cadmium and copper ions from wastewater .The effect of adsorption variable which include initial pH of solution , agitation speed, agitation time, initial concentration of cadmium and copper ions, and amount of adsorbent material were investigated in a batch process in order to obtain the maximum ions removal from wastewater .The results obtained from experimental investigation show that the percentage removal of metal ions increases with increasing pH and agitation speed until a maximize value after that it decreased with increasing pH and agitation speed. Also increases with increasing amount of adsorbent material and agitation time until a maximize value then reach a constant value approximately , and decreasing with increasing metal ions concentration .The maximum removal percent of cadmium and copper ions were 85.8% and 52.7 % respectively which obtained at pH equal 5.0, agitation speed 150 revolution per minute, agitation time 105 minute , metal ion concentration 40mg /L ,and adsorbent amount 1.5gm when using wheat bran as adsorbent material ,while obtained the maximum removal percent of cadmium and copper ions were 81.7% and 47.8 % which obtained at pH equal 6.0, and pH equal 5.0 respectively , agitation speed 150 revolution per minute, agitation time 90 minute ,metal ion concentration 40 mg /L ,and adsorbent amount 1.5gm when using okra waste as adsorbent material. From above result the wheat bran and okra waste was a best adsorbent material for removal cadmium and copper ions from wastewater but wheat bran slightly more effective than okra waste._x000D_
Accurately identifying the kind and amount of dissolved metal salts in wastewater used in oil refining processes is an iconic feature of ultraviolet and visible absorption spectroscopy. This method relies on the dissolved metal salts' ability to absorb light at certain wavelengths after reacting with it. The experiments were conducted in a lab setting with a broadband source (200-800 nm) to measure the absorbance of dissolved element salts and precisely identify the lowest concentration up to 2 ppm. A mixture of the mineral salts from oil refining operations was prepared and diluted to different concentrations using a standard solution. This allowed us to study and compare this result with the absorbance behavior of the wastewater from the Al-Dora Refinery. The two results reinforced that we can accurately estimate the detection parameters for the lowest water contamination. These materials are lead nitrate (PbNO3), phenol, calcium carbonate (CaCO3), sodium chloride (NaCl2), sulfide (SO4), and nitrate (NO3). At wavelengths of 340, 404, and 741 nm, the concentrations (10, 20, 30, 40, 50, 60, 70, 80, 90, and 100) ppm were found, and for the concentration of 10ppm, the absorbance (0.15323, 0.15326, and 0.14685) was found, respectively. The process that has been tested with varying concentrations is considered and simulates the variation in river water concentrations caused by the river's water level and flow rate changes by the effect of rain abundance and thawing. It is fast, accurate data analysis, and a lower cost compared with the other chemical analysis and conventional methods.
The ability of fungal waste biomass type White Agaricus Bisporus to biosorb Pb(II) ,Cr(III), Cd(II) and Co(II) from wastewater was investigated in batch process. Single and binary mixtures were used at low metal concentration wastewater treatment. The size of the biosorbent ranged 0.3-1 mm. The biosorption capacity of the biosorbent was evaluated under equilibrium conditions at 25 °C. Results indicated that the biosorption capacity of waste of fungi for the binary mixture was always lower than that for a single component system. Eight isotherm models were used to fit the experimental data of single system and Langmuir model was found a suitable to describe the biosorption data. The maximum uptake capacity (qe) of Pb(II), Cr(III), Cd(II) and Co(II) in single system was 158.73, 46.94, 40.16 and15.94 mg/g respectively with correlation coefficients 0.999,0.998,0.988 and 0.991 respectively. For binary system, four biosorption models were used to fit the experimental data. Extended Langmuir model gave the best fitting. The removal percentage of heavy metals onto fungal waste biomass was in order of Pb(II) > Cr(III) > Cd(II) > Co(II) in both single and binary system. The results show that the using waste of fungi as a biosorbent of heavy metals gave a higher uptake capacity of four heavy metals.
This work investigated the removal of the reactive green (R.G) dye from wastewater using the photo-Fenton process. Batch experiments were carried out to research the role of the Impacts of operating parameters. The dosage of H2O2; dosage Fe+2; pH; temperature, and irradiation time were examined. Maximum decolorization efficiencies green dye were achieved at the [H2O2]=100 ppm; [Fe2+]=20 ppm; pH 3; temperature=56 °C and irradiation time=90 min. This research focuses on modeling, kinetics and thermodynamics of the removal of pollutant (reactive green dye) of water. The results showed that the decolorization kinetic of R.G followed pseudo-first-order reaction kinetic. Also the thermodynamic parameters ?G?, ?H? and ?S? were determined using the Van't Hoff equation for the oxidation processes. The changes in Gibbs free energy showed the oxidation process under normal conditions is non-spontaneous.
Industrial activities significantly affect the environment by releasing many organic pollutants, including industrial dyes, phenols and antibiotics, which produce wastewater. Effective removal of these substances from wastewater has appeared as a noticeable research field owing to its environmental significance. Exorbitant operational expenses and the potential generation of supplementary pollutants load conventional techniques like adsorption, membrane separation, and coagulation. Semiconductor-based photocatalysis has effectively degraded organic contaminants into less toxic or biodegradable compounds. The construction of robust visible-light-sensitive photocatalytic hybrids for environmental decontamination is an inspiring task for researchers. The exceptional photocatalytic performance of silver halides (AgX, where X is I, Cl, and Br) has recently attracted significant consideration as photocatalysts. Moreover, the combination of silver halides with other photo-active semiconductors to create efficient visible-light-driven photocatalyst heterojunctions has significantly promoted the broader application of the photocatalysis process with enhanced efficiency. Ag-silver halides/semiconductors heterojunctions have developed as crucial components in efficient composites for photocatalysis through surface plasmonic actions, helping with visible light absorption. The current study overviews the most recent Ag and silver halide-based composite photocatalysts. Additionally, it provides an essential understanding of their promoted photocatalytic performances and their main applications in organic pollutant degradation. Moreover, the photocatalytic mechanisms and environmental applications of AgI and composites were discussed.
The purpose of this study is to investigate the potential of biochar derived from Peganum harmala (Pgh) seeds as an adsorbent material for wastewater treatment. Biochar is a cost-efficient, ecologically friendly, and effective bio-sorbent for a wide range of pollutants in wastewater. Researchers are investigating the production of biochar from novel biomass sources. Phosphoric acid (H3PO4) was utilized in a chemical activation technique to produce biochar at various concentrations (20%, 30%, and 40%). The pyrolysis process lasted three hours at 600°C in a tube furnace with an inert nitrogen gas atmosphere. Elemental analysis, Brunauer-Emmett-Teller (BET) nitrogen adsorption, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX), The biochar was characterized using several techniques, including elemental analysis, X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET) nitrogen adsorption, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX). The findings demonstrate the significant potential of Pgh seed-derived biochar as an inexpensive and ecologically acceptable sorbent material. A large surface area (691.58 m2g−1) was achieved at 600◦C for three hours with 40% H3PO4 activation.
In this study sunlight and UV radiation were used to compare the efficiency of decolorization of textile wastewater containing brilliant reactive red dye K-2BP (?max = 534 nm) by the advanced oxidation process (AOP) using (H2O2/sunlight, H2O2/UV, H2O2/TiO2/sunlight, and H2O2/TiO2/UV). The results studied the effect of solution pH, applied H2O2 concentration, TiO2 concentration (nanoparticle), and initial dye concentration were studied. The experimental results showed that decolorization percentage with H2O2/sunlight and TiO2/H2O2/sunlight under the following conditions: - reaction time 150 of minutes, [ 500 ppm] H2O2, [100 ppm] TiO2, pH=3, initial dye concentration =15 ppm and at ambient temperature were 95.7% and 98.42% respectively. For the same conditions using H2O2/UV, H2O2/TiO2 /UV, the percentage of decolorization were 97.85% and 96.33% respectively. The results also indicated that the sunlight is more economic and cost-effective than UV radiation.
The presence of heavy metal pollutants in refinery effluent significantly impacts the corrosion rate of carbon steel. The focus of this research is to analyze the impact of various inorganic pollutants, including copper, vanadium, nickel, and chromium ions, on the corrosion of carbon steel across different solutions. After conducting a thorough examination of various operating conditions, including pollutant concentration (ranging from 300-3000 ppm), temperature (30-60? C), and flow velocity (0-800 rpm). Our research shows that copper ions have the highest corrosion rate, with vanadium ions being a close second. Conversely, nickel and chromium had the most negligible impact on corrosion rate and, in some instances, even exhibited corrosion inhibition effects. It was also observed that an increase in flow velocity and temperature significantly amplified the corrosion rate of the metal ions investigated.
In this study, low cost biosorbent ? inactive biomass (IB) granules (dp=0.433mm) taken from drying beds of Al-Rustomia Wastewater Treatment Plant, Baghdad-Iraq were used for investigating the optimum conditions of Pb(II), Cu(II), and Ni(II) biosorption from aqueous solutions. Various physico-chemical parameters such as initial metal ion concentration (50 to 200 mg/l), equilibrium time (0-180 min), pH (2-9), agitation speed (50-200 rpm), particles size (0.433 mm), and adsorbent dosage (0.05-1 g/100 ml) were studied. Six mathematical models describing the biosorption equilibrium and isotherm constants were tested to find the maximum uptake capacities: Langmuir, Freundlich, Redlich–Peterson, Sips, Khan, and Toth models. The best fit to the Pb(II) and Ni(II) biosorption results was obtained by Langmuir model with maximum uptake capacities of 52.76 and 36.97 mg/g for these two ions respectively. While for Cu(II) the corresponding value was 38.07 mg/g obtained with Khan model. The kinetic study demonstrated that the optimum agitation speed was 400 rpm, at which the best removal efficiency and/or minimum surface mass transfer resistance (MSMTR) was achieved. A pseudo-second-order rate kinetic model gave the best fit to the experimental data (R2=0.99), resulting in mass transfer coefficient values of 42.84× , 1.57× , and 2.85× m/s for Pb(II), Cu(II), and Ni(II) respectively. The thermodynamic study showed that the biosorption process was spontaneous and exothermic in nature.